What is hydroxyl silicone oil?
Hits: 46
img
Hydroxyl silicone oil, also known as dimethyl hydroxyl silicone oil, is an organosilicon compound with a specific chemical structure. Its structural formula is
HO[(CH3)2SiO]nH is a linear polymer characterized by a main chain of repeated silicon-oxygen bonds, methyl groups as side chains, and hydroxyl groups at both ends. Hydroxyl silicone oil possesses numerous excellent properties and is widely applied in various fields.
I. Physical and Chemical Properties
Hydroxyl silicone oil usually appears as a colorless, transparent, odorless and tasteless oily liquid in physical form. It is soluble in organic solvents such as carbon tetrachloride, benzene, chloroform, ether and toluene, but insoluble in water and ethanol. Notably, low-viscosity hydroxyl silicone oil has a certain solubility in water. Its viscosity can range from very low to over ten thousand Pa·s, and the hydroxyl content can be from a few parts per ten thousand to over ten percent. The typical viscosity of hydroxyl silicone oil is ≤ 40 mPa·s (at 25°C), and its refractive index is within the range of 1.4000 to 1.4100 (at 25°C).
II. Preparation Method
The preparation methods of hydroxyl silicone oil are diverse, mainly including the following approaches:
Silane hydrolysis method: It is synthesized through the reaction of silane and water. Commonly, sodium hydroxide (NaOH) or potassium hydroxide (KOH) is dissolved in water to prepare a solution containing hydroxide ions, which then reacts with raw materials such as dimethyldichlorosilane to generate hydroxyl silicone oil.
2. Open-ring degradation method: It is formed by the open-ring addition of water to octamethylcyclotetrasiloxane (D4) under the action of acid or base.
3. Silicone rubber degradation method: It is produced by the degradation of silicone rubber in an autoclave with water and alkali as catalysts.
4. Degradation method of high molecular weight polydimethylsiloxane: It is obtained by catalytic degradation with potassium hydroxide and water under high pressure.
III. Main Uses
Hydroxyl silicone oil, due to its unique chemical structure and properties, has demonstrated significant application value in multiple fields:
1. Silicone rubber processing: Low-viscosity hydroxyl silicone oil is an excellent structural control agent in silicone rubber processing, which can replace diphenylsilanediol and simplify the process.
Improve artistry and enhance the performance of craftsmanship.
2. Fabric finishing: Hydroxyl silicone oil is widely used in fabric finishing, significantly enhancing the softness, smoothness and sewing performance of fabrics, while also imparting water repellency and other properties. During the fabric finishing process, hydroxyl silicone oil needs to be formulated into an emulsion for use, to improve its stability and adaptability.
3. Leather and Paper Treatment: As a waterproofing, softening and anti-sticking agent for leather and paper, hydroxyl silicone oil can effectively improve the surface properties of these materials.
4. Other fields: Hydroxyl silicone oil is also widely used in coatings, electronics and electrical appliances, biomedicine, food, and personal care, etc. In the aspect of polyurethane modification, the copolymerization of hydroxyl silicone oil and polyurethane can overcome the defects of single polymers and endow the copolymer products with excellent flexibility, water resistance and biocompatibility, etc.
IV. Market Prospects
With the advancement of technology and the development of industries, the market demand for hydroxyl silicone oil is constantly increasing. Especially in high-end textiles, functional materials, and emerging application fields such as biomedicine and electronic and electrical industries, the application prospects of hydroxyl silicone oil are very broad. It is expected that in the next few years, the global dimethyl hydroxyl silicone oil market will maintain a stable growth trend, and the Chinese market will also play an increasingly important role.
In conclusion, as an organic silicon compound with excellent performance, hydroxyl silicone oil has demonstrated significant application value and development potential in multiple fields. With the continuous advancement of technology and the continuous expansion of the market, the application prospects of hydroxyl silicone oil will be even broader.