How much do you know about the characteristics of methyl silicone oil?
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What is methyl silicone oil: Methyl silicone oil is generally a colorless, odorless, non-toxic liquid that is not volatile. It is insoluble in water, methanol, and ethylene glycol, and can be miscible with benzene, dimethyl ether, carbon tetrachloride, or kerosene. It is slightly soluble in acetone, dioxane, ethanol, and butanol. Due to the weak intermolecular forces between methyl silicone oil molecules and the helical structure of the molecular chain, the organic groups can freely rotate. Therefore, it has excellent spreading performance, lubricity, high-temperature and low-temperature resistance, weather resistance, radiation resistance, high flash point, low surface tension, and physiological inertness, and is widely used in industries such as cosmetics, machinery, electrical, textiles, coatings, medicine, and food.
Methyl silicone oil is a linear polyorganosiloxane with Si-O-Si as the main chain, with 2 methyl groups connected to each Si atom, and a trimethylsiloxy group as the end group. It is in a liquid state at room temperature. Its structural formula is as follows:
The characteristics of methyl silicone oil
Methyl silicone oil possesses many unique properties:
■ Good heat resistance
The silicon oil molecules have a structure similar to that of inorganic polymers because their main chain is composed of -Si-O-Si- bonds. Due to their high bond energy, these molecules possess excellent heat resistance.
■ Excellent oxidation resistance and weather resistance
■ Excellent electrical insulation performance
Silicone oil has excellent dielectric properties. Its electrical characteristics change very little with temperature and frequency. The dielectric constant decreases with the increase of temperature, but the change is very small. The power factor of silicone oil is low and increases with the rise of temperature, but there is no regularity in its change with frequency. The volume resistivity decreases with the increase of temperature.
■ Excellent water repellency
Although the main chain of silicone oil is composed of polar bonds Si-O, the non-polar alkyl groups on the side chains are oriented outward, preventing water molecules from entering the interior and exerting a hydrophobic effect. The interfacial tension of silicone oil with water is approximately 42 dynes per centimeter. When diffusing on the glass surface, due to the water-repellent property of silicone oil, a contact angle of approximately 103° is formed, which can be comparable to that of paraffin.
■ Low viscosity coefficient
The viscosity of silicone oil is low and it changes little with temperature, which is related to the helical structure of the silicone oil molecules. Silicone oil is one of the types of liquid lubricants that have the best viscosity-temperature characteristics. This property of silicone oil is of great significance for damping equipment.
■ High compressive resistance
Due to the helical structure characteristics of silicon oil molecules and the large distance between molecules, it has high compressive resistance. Utilizing this property of silicon oil, it can be used as a liquid spring, which can significantly reduce the volume compared to mechanical springs.
■ Low surface tension
Low surface tension is a characteristic of silicone oil. Low surface tension indicates high surface activity. Therefore, silicone oil has excellent anti-foaming and anti-bubbling properties, as well as the ability to isolate from other substances and provide lubrication.
■ Non-toxic, odorless and physiologically inert
From a physiological perspective, siloxane polymers are one of the least reactive compounds known. Dimethyl silicone oil is inert to living organisms and does not cause rejection reactions in the animal body. Therefore, they have been widely applied in departments such as surgery and internal medicine, medicine, food, and cosmetics.
■ Good lubrication performance
Silicone oil possesses many excellent properties as a lubricant, such as a high flash point, a low freezing point, thermal stability, small viscosity variation with temperature, non-corrosion of metals, no adverse effects on rubber, plastics, coatings, organic varnishes, low surface tension, and easy spreading on metal surfaces. To improve the lubricity of silicone oil between steel surfaces, lubricant additives that can be miscible with silicone oil can be added. Introducing chlorophenyl groups onto the silicon-oxygen chain or replacing the dimethyl group with trifluoropropylmethyl can significantly enhance the lubrication performance of silicone oil.